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JEE Main levelSingle correct optionDifficulty 2 of 3cc196

In the Mond process, impure nickel is purified because:

  1. A forms at low temperature and decomposes at a higher temperature to give pure Ni
  2. B is converted to a soluble cyanide complex and then reduced
  3. C forms at high temperature and decomposes at low temperature
  4. Dall metals in the impure sample form volatile carbonyls that condense differently

Answer: A

Nickel reacts with at about - to form volatile , leaving the other metals behind. The reaction has negative (4 mol gas to 1 mol), so heating the vapour to about - reverses it and deposits pure nickel.
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