JEE Main levelSingle correct optionDifficulty 2 of 3cc196
In the Mond process, impure nickel is purified because:
ANi(CO)X4 forms at low temperature and decomposes at a higher temperature to give pure Ni
BNi is converted to a soluble cyanide complex and then reduced
CNi(CO)X4 forms at high temperature and decomposes at low temperature
Dall metals in the impure sample form volatile carbonyls that condense differently
Answer: A
Nickel reacts with CO at about 330-350K to form volatile Ni(CO)X4, leaving the other metals behind. The reaction has negative ΔS (4 mol gas to 1 mol), so heating the vapour to about 450-470K reverses it and deposits pure nickel.