JEE Advanced levelSingle correct optionDifficulty 3 of 3cc149
A sample of 2.665 g of green CrClX3⋅6HX2O (molar mass 266.5 g/mol, Cr coordination number 6) gives 1.435 g of AgCl (molar mass 143.5 g/mol) with excess AgNOX3. The mass of lattice (non-coordinated) water per sample, in g, is (HX2O=18 g/mol)
A0.36
B0.18
C0.54
D1.08
Answer: A
Moles of complex =2.665/266.5=0.0100 and moles of AgCl=1.435/143.5=0.0100, so 1 free chloride per formula unit. The complex is [CrClX2(HX2O)X4]Cl⋅2HX2O with 2 lattice waters. Mass =0.0100×2×18=0.36 g.