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JEE Advanced levelSingle correct optionDifficulty 3 of 3cc149

A sample of 2.665 g of green (molar mass 266.5 g/mol, Cr coordination number 6) gives 1.435 g of (molar mass 143.5 g/mol) with excess . The mass of lattice (non-coordinated) water per sample, in g, is ( g/mol)

  1. A0.36
  2. B0.18
  3. C0.54
  4. D1.08

Answer: A

Moles of complex and moles of , so 1 free chloride per formula unit. The complex is with 2 lattice waters. Mass g.
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