JEE Main levelNumerical answerDifficulty 2 of 3ck182
The decomposition 2HX2OX22HX2O+OX2 of 50.0mL of solution gives 33.6mL of OX2 (at STP, molar volume 22.4Lmol−1) in the first 10.0min. Taking the volume as constant, find the average rate of disappearance of HX2OX2 in units of 10−3Mmin−1 (two decimal places).
Numerical answer type, answer in 1e-3 M/min, tolerance 0.01.
Answer: 6 1e-3 M/min
Moles of OX2 = 33.6×10−3/22.4=0.0015 mol; HX2OX2 consumed is twice this, 0.0030 mol, i.e. 0.0600M in 0.0500 L. Average rate =0.0600/10.0=6.00×10−3Mmin−1.