JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ck165
A plot of lnk against 1/T is linear with slope −5000 K and intercept 18 (k in s−1). Use R=8.314Jmol−1K−1, e18=6.57×107, e8=2981. Which statements are correct?
Ak at 250 K is about 0.135 s−1 (e−2=0.1353)
BA=6.57×107s−1
Ck at 500 K is about 2981 s−1
DEa=95.7kJmol−1
Answer: A, B, C
Ea=slope×R=5000×8.314=41.57 kJ/mol, so the claimed value with 2.303 is wrong. A=e18=6.57×107. At 500 K, lnk=18−10=8, k=2981; at 250 K, lnk=18−20=−2, k=0.135.