JEE Main levelSingle correct optionDifficulty 2 of 3ck016
A gaseous reaction has the rate law rate =k[A][B]2. The volume of the reaction vessel is reduced to one-third of its original value at constant temperature, with no change in the amounts of gases. The rate becomes
A9 times the original
B3 times the original
C27 times the original
D81 times the original
Answer: C
Concentration is inversely proportional to volume, so every concentration becomes 3 times larger. The rate is of third order overall: 31+2=33=27.