NEET levelSingle correct optionDifficulty 1 of 3ce166
For the dissociation PClX5(g)PClX3(g)+ClX2(g), let D be the vapour density calculated for undissociated PClX5 and d the vapour density of the equilibrium mixture at the same temperature and pressure. The degree of dissociation α is
AD−dD
B2dd−D
CdD−d
DDD−d
Answer: C
For one mole of reactant, total moles at equilibrium are 1+α, and vapour density is inversely proportional to total moles at fixed mass, so D/d=1+α. Hence α=(D−d)/d.