JEE Advanced levelNumerical answerDifficulty 3 of 3ce150
A 3.0L flask holds 0.30 mol NOX2 and a 2.0L flask holds 0.10 mol NX2OX4, at the same temperature. For NX2OX4(g)2NOX2(g), Kc=0.0065molL−1 at this temperature. When the stopcock between the flasks is opened, the gases mix instantly. Calculate Qc/Kc at that instant (one decimal).
Numerical answer type, tolerance 0.1.
Answer: 27.7
Total volume is 5.0L: [NOX2]=0.30/5.0=0.060 and [NX2OX4]=0.10/5.0=0.020molL−1. Qc=(0.060)2/0.020=0.180. Qc/Kc=0.180/0.0065=27.692, i.e. 27.7, so the reaction shifts strongly backward.