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JEE Advanced levelSingle correct optionDifficulty 3 of 3ce148

Two different equilibrium mixtures of the same reaction at the same temperature are prepared in two vessels of equal volume: mixture 1 has , and mixture 2 has , (all in ). The vessels are connected and the gases mix, giving a total volume that is twice one vessel, at the same temperature. Immediately after mixing, the reaction

  1. Aproceeds backward, because
  2. Bis at equilibrium, because both parts were at equilibrium
  3. Ccannot be decided without knowing the volume of each vessel
  4. Dproceeds forward, because

Answer: D

Each mixture has . After mixing, concentrations are averaged: and . , so the net reaction is forward. The quotient is not linear in concentration, so mixing equilibrium mixtures does not preserve equilibrium.
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