JEE Advanced levelSingle correct optionDifficulty 3 of 3ce096
For the gas-phase reaction CHX4(g)+HX2O(g)CO(g)+3HX2(g), the ratio Kp/Kc=3600 when pressures are in atm and concentrations in molL−1. Taking R=0.0821Latmmol−1K−1, the temperature (in K) is approximately
A43849
B731
C60
D21924
Answer: B
Δn=4−2=+2, so Kp/Kc=(RT)2=3600. Taking the square root, RT=60 and T=60/0.0821=731 K.