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JEE Advanced levelSingle correct optionDifficulty 3 of 3ce093

A 1.0 L vessel at 300 K contains 0.368 g of and 0.368 g of (molar masses 92 and 46 g/mol). For , atm at 300 K. Take . Which conclusion is correct?

  1. ANo conclusion is possible without the total pressure
  2. BThe reaction proceeds forward, since is smaller than
  3. CThe mixture is at equilibrium, because the masses of the two gases are equal
  4. DThe reaction proceeds backward, since exceeds

Answer: D

Moles: = 0.368/92 = 0.0040 mol, = 0.368/46 = 0.0080 mol, so concentrations are 0.0040 and 0.0080 mol/L. . . Since , the net change is backward. Comparing with directly is wrong because they differ by the factor .
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