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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ce044

1.0 mol of dissociates () to the extent of 50% at a total equilibrium pressure of 1.00 atm and temperature . Which statements are correct?

  1. A atm at
  2. BThe mole fraction of at equilibrium is 0.50
  3. CAt the same and a total pressure of 4.00 atm, the degree of dissociation is about 0.28
  4. DAt the same and a total pressure of 4.00 atm, the degree of dissociation is exactly 0.25

Answer: A, C

atm, so (A) is true. The mole fraction of is , not 0.50, so (B) is false. At 4.00 atm, , so (C) is true; halving is not exact, so (D) is false.
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