JEE Advanced levelSingle correct optionDifficulty 3 of 3ce045
For 2SOX2(g)+OX2(g)2SOX3(g), Kc=40Lmol−1 at a given temperature. An equilibrium mixture is disturbed by adding OX2 at constant volume and temperature. At the new equilibrium [OX2]=0.25M. The new ratio [SOX3]/[SOX2] is
A3.16
B10.00
C6.32
D2.00
Answer: A
From Kc=[SOX3]2/([SOX2]2[OX2]), ([SOX3]/[SOX2])2=Kc[OX2]=40×0.25=10.0. Taking the square root, the ratio is 3.162.