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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3cb208

Relative to (m.p. ), which of the following have a lower melting point mainly because of significant polarisation (covalent character)?

  1. A
  2. B
  3. C
  4. D

Answer: A, B, C

has an -electron cation, while and are small and highly charged, so , and are partly covalent and melt (or sublime) at lower temperatures. has a doubly charged cation with the hardly polarisable , so it is ionic with a high lattice energy and a higher melting point (about ).
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