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JEE Advanced levelSingle correct optionDifficulty 3 of 3cb206

Strong heating of gives (or basic chloride) and instead of anhydrous . The underlying reason is that

  1. Athe small, doubly charged strongly polarises coordinated water, favouring hydrolysis with loss of
  2. B sublimes on heating
  3. C is oxidised by the water of crystallisation
  4. D is reduced to by water

Answer: A

has a high ionic potential and withdraws electron density from the O-H bonds of the coordinated water, making them easy to cleave. Proton transfer to then releases and leaves an oxide or hydroxide chloride. No redox change occurs, and does not sublime.
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