JEE Advanced levelSingle correct optionDifficulty 3 of 3cb205
Ionic potential is taken as charge/radius with radii LiX+=76, NaX+=102, MgX2+=72, AlX3+=54 and BeX2+=45pm. Which cation has an ionic potential closest to that of BeX2+, consistent with the diagonal relationship in the periodic table?
ANaX+
BLiX+
CMgX2+
DAlX3+
Answer: D
Compute ϕ in charge per pm: Be 0.0444, Al 0.0556, Mg 0.0278, Li 0.0132, Na 0.0098. The nearest to Be is Al, with a difference of 0.0111, whereas Mg differs by 0.0167. This matches the Be-Al diagonal relationship.