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JEE Advanced levelSingle correct optionDifficulty 3 of 3co203

Ethanoic acid is heated with methanol labelled as in the presence of conc. to give ester X. X is then completely hydrolysed with excess aqueous under reflux. Assuming acyl-oxygen cleavage in both steps, the is finally found in

  1. Amethanol only
  2. Bsodium ethanoate only
  3. Cwater formed in the first step
  4. Dboth methanol and sodium ethanoate

Answer: A

Esterification keeps the alcohol oxygen in the ester, giving . In alkaline hydrolysis, attacks the carbonyl carbon and the alkoxide () leaves, which gets protonated. So the label ends in methanol, not in the ethanoate.
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