JEE Advanced levelNumerical answerDifficulty 3 of 3bm083
Alanine has pKa1=2.34. Ignoring the anionic form, at what pH is the ratio of zwitterion to cation equal to 20 : 1? Give the answer to two decimal places (use log2=0.3010).
Numerical answer type, tolerance 0.02.
Answer: 3.64
For HX3NX+−CHR−COOH⇌HX3NX+−CHR−COOX−, pH=pKa1+log([zwitterion]/[cation])=2.34+log20. log20=1+0.3010=1.3010, so pH = 3.641≈3.64.