JEE Advanced levelSingle correct optionDifficulty 3 of 3bm078
0.15 mol of aspartic acid hydrochloride, HOOC−CHX2−CH(NHX3X+Cl−)−COOH, is treated with just enough NaOH to convert it completely into NaOOC−CHX2−CH(NHX2)−COONa (plus NaCl and water). The amount of NaOH required is
A0.30 mol
B0.15 mol
C0.60 mol
D0.45 mol
Answer: D
Each mole of the salt has three acidic protons: two −COOH and one −NHX3X+ (the chloride is the counter ion of the ammonium group). Moles of NaOH = 3×0.15=0.45 mol.