JEE Main levelSingle correct optionDifficulty 2 of 3ap096
Sodium phenoxide is heated with COX2 at 4-7 atm and about 400 K, and the product is then acidified with HX3OX+. The main product is
Abenzoic acid
B4-hydroxybenzoic acid
Cbenzene-1,2-dicarboxylic acid
D2-hydroxybenzoic acid
Answer: D
This is the Kolbe-Schmidt reaction. The weak electrophile COX2 attacks the phenoxide ion at the ortho position under these conditions, giving sodium salicylate. Acidification liberates salicylic acid, 2-hydroxybenzoic acid.