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JEE Main levelSingle correct optionDifficulty 2 of 3ap096

Sodium phenoxide is heated with at 4-7 atm and about 400 K, and the product is then acidified with . The main product is

  1. Abenzoic acid
  2. B4-hydroxybenzoic acid
  3. Cbenzene-1,2-dicarboxylic acid
  4. D2-hydroxybenzoic acid

Answer: D

This is the Kolbe-Schmidt reaction. The weak electrophile attacks the phenoxide ion at the ortho position under these conditions, giving sodium salicylate. Acidification liberates salicylic acid, 2-hydroxybenzoic acid.
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