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NEET levelSingle correct optionDifficulty 1 of 3ap093

Phenol is treated with excess bromine water. The product is

  1. A2-bromophenol
  2. B2,4,6-tribromophenol
  3. C4-bromophenol
  4. Dbromobenzene

Answer: B

The OH group strongly activates the ring, and in a polar solvent like water phenol ionises partly. Substitution occurs at all three positions ortho and para to OH, giving a white precipitate of 2,4,6-tribromophenol.
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