NEET levelSingle correct optionDifficulty 1 of 3ap075
On heating with dilute HX2SOX4, pinacol gives pinacolone, which is
A2,3-dimethylbutanal
B3,3-dimethylbutan-2-one
C3-methylpentan-2-one
D2,3-dimethylbuta-1,3-diene
Answer: B
Loss of water gives (CHX3)X2CX+−C(OH)(CHX3)X2, then a methyl shift gives a protonated ketone. Loss of HX+ gives CHX3−CO−C(CHX3)X3, which is 3,3-dimethylbutan-2-one (pinacolone).