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Alcohols, Phenols and Ethers
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Pinacol-pinacolone and related rearrangements
NEET level
Single correct option
Difficulty 1 of 3
ap074
Pinacol, the starting diol of the pinacol-pinacolone rearrangement, has the IUPAC name
A
2,3-dimethylbutane-2,3-diol
B
2,3-dimethylbutane-1,2-diol
C
3,3-dimethylbutane-1,2-diol
D
2,2-dimethylbutane-1,3-diol
Answer: A
Pinacol is
(
CH
X
3
)
X
2
C
(
OH
)
−
C
(
OH
)
(
CH
X
3
)
X
2
: a butane chain with a methyl and a hydroxyl on each of C2 and C3. This is 2,3-dimethylbutane-2,3-diol.
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