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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ap055

Which of the following give a white precipitate with excess bromine water?

  1. Aphenol
  2. B3-methylphenol
  3. Ccyclohexanol
  4. Dbenzoic acid

Answer: A, B

Phenols have an activated ring and are brominated at all free ortho and para positions to give insoluble polybromo derivatives, 2,4,6-tribromophenol and 2,4,6-tribromo-3-methylphenol respectively. Cyclohexanol is saturated and benzoic acid's ring is deactivated, so neither gives a precipitate.
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