JEE Main levelOne or more correct optionsDifficulty 2 of 3td043
One mole of an ideal gas is taken from state 1 to state 2. Which statements are correct?
AIn an adiabatic free expansion into vacuum in an insulated container, ΔSgas>0 and ΔSsurr=0.
BIn a reversible adiabatic expansion, ΔSgas=0.
CFor an isothermal expansion against a constant external pressure, ΔSgas equals that of the reversible isothermal path between the same states.
DIn a reversible isothermal expansion, ΔSuniverse>0.
Answer: A, B, C
(A) Volume increases at constant T so ΔSgas=Rln(V2/V1)>0; no heat reaches the surroundings: true. (B) qrev=0 so ΔS=0: true. (C) S is a state function: true. (D) A reversible process has ΔSuniverse=0: false.