JEE Advanced levelSingle correct optionDifficulty 3 of 3td013
One mole of a monatomic ideal gas at 2.0atm and 10L is expanded at constant pressure to 20L, and then cooled at constant volume until the pressure is 1.0atm. Taking 1Latm=101.3J, the net heat absorbed by the gas in the two steps is
A−2026J
B2026J
C0
D4052J
Answer: B
Initial PV=2×10=20Latm and final PV=1×20=20Latm, so the final temperature equals the initial one and ΔU=0 (ideal gas). Work is done only in step 1: w=−PΔV=−2×10=−20Latm=−2026J. Hence q=−w=+2026J.