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Thermodynamics and Thermochemistry
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First law, work, heat, internal energy, enthalpy
JEE Main level
One or more correct options
Difficulty 2 of 3
td010
At
300
K
, treating all gases as ideal, which of the following statements is/are correct?
A
For
2
H
X
2
(
g
)
+
O
X
2
(
g
)
2
H
X
2
O
(
l
)
,
Δ
H
<
Δ
U
.
B
For
CaCO
X
3
(
s
)
CaO
(
s
)
+
CO
X
2
(
g
)
,
Δ
H
−
Δ
U
=
RT
.
C
For
H
X
2
(
g
)
+
I
X
2
(
g
)
2
HI
(
g
)
,
Δ
H
=
Δ
U
.
D
For
C
(
graphite
)
+
O
X
2
(
g
)
CO
X
2
(
g
)
,
Δ
H
−
Δ
U
=
RT
.
Answer: A, B, C
Use
Δ
H
−
Δ
U
=
Δ
n
g
RT
. (A)
Δ
n
g
=
0
−
3
=
−
3
, so
Δ
H
<
Δ
U
: true. (B)
Δ
n
g
=
+
1
: true. (C)
Δ
n
g
=
2
−
2
=
0
: true. (D)
Δ
n
g
=
1
−
1
=
0
, so
Δ
H
=
Δ
U
, not
RT
: false.
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