JEE Advanced levelNumerical answerDifficulty 3 of 3sc161
A protein sol containing 8.0gL−1 of the protein supports a water column of height 3.2cm at osmotic equilibrium at 300K. Take the density of water as 1000kgm−3, g=9.8ms−2 and R=8.314Jmol−1K−1. Find the molar mass of the protein in gmol−1, to the nearest integer.
Numerical answer type, answer in g/mol, tolerance 5.
Answer: 63628 g/mol
Osmotic pressure = ρgh=1000×9.8×0.032=313.6 Pa. With π=(w/M)RT and w=8.0kgm−3, M=wRT/π=8.0×8.314×300/313.6=63.63kgmol−1. This is 63628 g/mol.