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JEE Main levelSingle correct optionDifficulty 2 of 3si162

Potassium phthalimide is heated with bromoethane to give A, and A is heated with aqueous to give B and disodium phthalate. B is

  1. Aethanamine
  2. BN-ethylphthalimide
  3. Ctriethylamine
  4. Ddiethylamine

Answer: A

In the Gabriel synthesis the N-alkylphthalimide (A, N-ethylphthalimide) is hydrolysed to the primary amine (B) and the phthalate. Only the primary amine is formed, since the nitrogen is blocked from further alkylation.
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