JEE Main levelSingle correct optionDifficulty 2 of 3si162
Potassium phthalimide is heated with bromoethane to give A, and A is heated with aqueous NaOH to give B and disodium phthalate. B is
Aethanamine
BN-ethylphthalimide
Ctriethylamine
Ddiethylamine
Answer: A
In the Gabriel synthesis the N-alkylphthalimide (A, N-ethylphthalimide) is hydrolysed to the primary amine CHX3CHX2NHX2 (B) and the phthalate. Only the primary amine is formed, since the nitrogen is blocked from further alkylation.