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JEE Main levelSingle correct optionDifficulty 2 of 3si149

A hydrocarbon gives a white precipitate with ammoniacal and adds two moles of over Ni to give unbranched pentane. The hydrocarbon is

  1. Apent-2-yne
  2. Bpent-1-yne
  3. Cpenta-1,3-diene
  4. Dpenta-1,4-diene

Answer: B

The precipitate with ammoniacal needs a terminal alkyne with an acidic . Two moles of and an unbranched product point to . Pent-2-yne is internal and the dienes do not give the precipitate.
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