JEE Main levelSingle correct optionDifficulty 2 of 3si149
A hydrocarbon CX5HX8 gives a white precipitate with ammoniacal AgNOX3 and adds two moles of HX2 over Ni to give unbranched pentane. The hydrocarbon is
Apent-2-yne
Bpent-1-yne
Cpenta-1,3-diene
Dpenta-1,4-diene
Answer: B
The precipitate with ammoniacal AgNOX3 needs a terminal alkyne with an acidic C≡C−H. Two moles of HX2 and an unbranched product point to CHX3CHX2CHX2C≡CH. Pent-2-yne is internal and the dienes do not give the precipitate.