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JEE Main levelSingle correct optionDifficulty 2 of 3si135

How many primary amines are there among the constitutional isomers of (all of which are saturated acyclic amines)? Each of them gives the carbylamine test. Count constitutional isomers only (no stereoisomers).

  1. A3
  2. B4
  3. C8
  4. D6

Answer: B

A primary amine is with R = , and there are four butyl groups (n-butyl, sec-butyl, isobutyl, tert-butyl). So butan-1-amine, butan-2-amine, 2-methylpropan-1-amine and 2-methylpropan-2-amine give 4. The other 4 isomers are secondary (3) or tertiary (1), giving 8 in all.
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