NEET levelSingle correct optionDifficulty 1 of 3si133
Benzene is treated with CHX3Cl in the presence of anhydrous AlClX3 to give A. A is heated with alkaline KMnOX4 and then acidified to give B. B is
Abenzaldehyde
Bbenzoic acid
Cbenzyl alcohol
Dphenylacetic acid
Answer: B
Friedel-Crafts alkylation gives toluene (A). Alkaline KMnOX4 oxidises any alkyl side chain with a benzylic hydrogen completely to −COOH, so B is CX6HX5COOH (benzoic acid), not an intermediate oxidation product.