MolSynapsequestion bank
MolSynapse / Question bank / Structural Identification and Practical Organic Chemistry / Distinguishing tests for functional groups
JEE Advanced levelOne or more correct optionsDifficulty 3 of 3si005

Which of the following pairs can be distinguished by the single reagent indicated? (more than one may be correct)

  1. Apentan-2-one and pentan-3-one:
  2. Bpropanal and propanone: 2,4-DNP
  3. Cethanol and methanol:
  4. Dphenol and cyclohexanol: neutral

Answer: A, C, D

Ethanol gives iodoform but methanol does not; pentan-2-one gives it but pentan-3-one does not; phenol gives a violet colour but cyclohexanol does not. Propanal and propanone are both carbonyl compounds and both give 2,4-DNP precipitates, so that pair is not distinguished.
Practice Structural Identification and Practical Organic Chemistry More on Distinguishing tests for functional groups

More questions on Distinguishing tests for functional groups