JEE Main levelSingle correct optionDifficulty 2 of 3si002
But-1-yne and but-2-yne can be distinguished by
Aammoniacal silver nitrate
Bcold dilute alkaline KMnOX4
Chydrogen over Ni catalyst
DBrX2/CClX4
Answer: A
But-1-yne is a terminal alkyne and gives a white precipitate of silver butynide; but-2-yne does not. Both decolourise bromine in CClX4 and alkaline permanganate, and both are hydrogenated to butane.