Answer: A
Geometrical isomerism requires each doubly bonded carbon to carry two different groups. P, pent-2-ene CHX3CH=CHCX2HX5, has H and CHX3 on one carbon and H and CX2HX5 on the other: cis/trans isomers exist. Q (2-methylbut-2-ene) has two methyls on one carbon, R (but-1-ene) and S (2-methylpropene) have two hydrogens on the terminal carbon; each of these has a carbon with two identical groups, so no geometrical isomerism.