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NEET levelSingle correct optionDifficulty 1 of 3st118

Among the conformations of butane obtained by rotation about the C2-C3 bond, the most stable one is

  1. Agauche (staggered, methyl groups 60 degrees apart)
  2. Bpartially eclipsed (methyl groups 120 degrees apart)
  3. Canti (staggered, methyl groups 180 degrees apart)
  4. Dfully eclipsed (methyl groups 0 degrees apart)

Answer: C

The anti conformer has the two bulky methyl groups as far apart as possible and no torsional strain, so it is the global energy minimum. Gauche is a local minimum, about 3.8 kJ/mol higher because of methyl-methyl steric strain.
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