NEET levelSingle correct optionDifficulty 1 of 3st111
A solution of an optically active compound has specific rotation +24.0 (units: degree dm−1 (g/mL)−1). It is placed in a polarimeter tube 2.0 dm long at concentration 0.30 g/mL. Using α=[α]lc, the observed rotation is
A+7.2∘
B+48.0∘
C+14.4∘
D+144∘
Answer: C
Observed rotation = specific rotation x path length (dm) x concentration (g/mL). α=24.0×2.0×0.30=14.4∘. Using the length in cm (144) or dropping a factor gives the wrong options.