JEE Main levelNumerical answerDifficulty 2 of 3so173
2.5g of a non-volatile non-electrolyte dissolved in 50g of benzene raises its boiling point by 0.85K. Given Kb(benzene)=2.53Kkgmol−1, find the molar mass of the solute in gmol−1, to the nearest integer.
Numerical answer type, answer in g/mol, tolerance 1.
Answer: 149 g/mol
ΔTb=KbMWw×1000, so M=ΔTbW1000Kbw=0.85×501000×2.53×2.5=148.82≈149gmol−1.