JEE Advanced levelNumerical answerDifficulty 3 of 3so154
At a certain temperature the vapour pressure of pure water is 760.0 mmHg. A solution of 18.0 g of a non-volatile non-electrolyte in 90.0 g of water (18gmol−1) has a vapour pressure of 745.1 mmHg. Use PP0−P=n1n2. Find the molar mass of the solute in gmol−1 (nearest integer).
Numerical answer type, answer in g/mol, tolerance 1.
Answer: 180 g/mol
n1=90.0/18=5.00 mol. (P0−P)/P=(760.0−745.1)/745.1=0.02000, so n2=0.02000×5.00=0.1000 mol. M=18.0/0.1000=180.0gmol−1, i.e. about 180.