JEE Advanced levelNumerical answerDifficulty 3 of 3so153
Liquids A and B form an ideal solution. At a given temperature PA0=300 torr and PB0=100 torr. The vapour in equilibrium with a solution has mole fraction of A equal to 0.60. Find the total vapour pressure (torr) of the solution, to the nearest integer.
Numerical answer type, answer in torr, tolerance 1.
Answer: 167 torr
Let liquid mole fraction be x. yA=300x/[300x+100(1−x)]=3x/(1+2x)=0.60, so 3x=0.60+1.2x and x=1/3. P=300(1/3)+100(2/3)=100+66.67=166.67 torr, i.e. about 167 torr.