JEE Main levelSingle correct optionDifficulty 2 of 3so129
At 25∘C the vapour pressure of pure water is 23.8 torr. Find the vapour pressure of a solution of 10g urea (molar mass 60gmol−1) in 90g water. Use the ideal Raoult's law expression.
A21.42torr
B24.57torr
C23.03torr
D0.77torr
Answer: C
n2=10/60=0.1667 mol and n1=90/18=5.00 mol, so x2=0.1667/5.1667=0.0323. P=P0(1−x2)=23.8×0.9677=23.03 torr. The value 0.77 torr is just the lowering, not the final pressure.