NEET levelSingle correct optionDifficulty 1 of 3so116
A non-volatile solute (0.25 mol) is dissolved in 4.75 mol of a volatile solvent whose vapour pressure when pure is 200 torr. Assuming Raoult's law, the vapour pressure of the solution is
A190torr
B10torr
C210.5torr
D180torr
Answer: A
x2=0.25/(0.25+4.75)=0.05 and P=x1P0=0.95×200=190 torr. The value 10 torr is only the lowering P0−P. The solution pressure must be below the pure-solvent value of 200 torr.