JEE Advanced levelSingle correct optionDifficulty 3 of 3so092
A non-electrolyte X (15gL−1) is isotonic at the same temperature with a solution containing 5.85gL−1NaCl (molar mass 58.5, complete dissociation) and 9.0gL−1 glucose (molar mass 180gmol−1). The molar mass of X (in gmol−1) is
A100
B75
C120
D60
Answer: D
Particle concentration of the reference solution =2×(5.85/58.5)+9.0/180=0.20+0.05=0.25molL−1. X must have the same concentration: 15/M=0.25, so M=60gmol−1.