JEE Main levelSingle correct optionDifficulty 2 of 3so062
Ethylene glycol (molar mass 62gmol−1) is added to 1.00kg of water so that the solution freezes at −9.3∘C. Take Kf=1.86Kkgmol−1 and treat ethylene glycol as a non-electrolyte. The mass of ethylene glycol required is
A155g
B31g
C620g
D310g
Answer: D
ΔTf=9.3K, so m=9.3/1.86=5.0molkg−1. For 1.00kg water, moles =5.0 and mass =5.0×62=310g.