JEE Advanced levelSingle correct optionDifficulty 3 of 3so017
A gas dissolves in 500g of water to give a solution containing 0.0150mol of the gas. For this gas KH=3000bar with p=KHx (x is the mole fraction in solution). Taking M(HX2O)=18gmol−1, the equilibrium partial pressure of the gas above the solution is
A0.81bar
B3.24bar
C1.62bar
D16.2bar
Answer: C
Moles of water =500/18=27.78. x=0.0150/(0.0150+27.78)=5.397×10−4. p=KHx=3000×5.397×10−4=1.62bar. Using a 1 kg basis for the water would halve this value.