JEE Advanced levelOne or more correct optionsDifficulty 3 of 3sb216
Which of the following statements about plaster of Paris are correct?
AIt contains one molecule of water of crystallisation per formula unit of CaSOX4.
BOn mixing with water it sets to a hard mass of gypsum, with a slight expansion in volume.
CIt is formed by heating gypsum to about 393 K.
DHeating it above 473 K gives anhydrous CaSOX4 that sets very slowly.
Answer: B, C, D
CaSOX4⋅2HX2O gives the hemihydrate near 393 K, which hydrates and recrystallises with a small expansion. Overheating gives dead burnt plaster. The hemihydrate has 21 water per CaSOX4, not one.