JEE Advanced levelSingle correct optionDifficulty 3 of 3sb102
Anhydrous sodium sulphate (14.2 g) is heated with excess carbon: NaX2SOX4+4CNaX2S+4CO. The carbon monoxide produced is then burnt completely in air to carbon dioxide. Using Na 23, S 32, O 16 and 22.4 L per mol at STP, the volume of COX2 formed is
A2.24 L
B8.96 L
C4.48 L
D17.92 L
Answer: B
Molar mass of NaX2SOX4 is 142 g/mol, so 14.2 g is 0.100 mol, which gives 4×0.100=0.400 mol CO. 2CO+OX22COX2 gives 0.400 mol COX2, whose volume at STP is 0.400×22.4=8.96 L.