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JEE Main levelSingle correct optionDifficulty 2 of 3sb095

Take ionic radii = 167 pm and = 181 pm. Using the radius ratio ranges 0.225-0.414 (tetrahedral), 0.414-0.732 (octahedral) and 0.732-1.000 (cubic), the coordination number of Cs+ in CsCl is

  1. A6
  2. B12
  3. C8
  4. D4

Answer: C

The radius ratio is , which lies in the cubic range 0.732-1.000. A cubic hole means each Cs+ is surrounded by 8 chloride ions, so the coordination number is 8 (6 would apply to NaCl).
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