JEE Main levelSingle correct optionDifficulty 2 of 3sb095
Take ionic radii CsX+ = 167 pm and ClX− = 181 pm. Using the radius ratio ranges 0.225-0.414 (tetrahedral), 0.414-0.732 (octahedral) and 0.732-1.000 (cubic), the coordination number of Cs+ in CsCl is
A6
B12
C8
D4
Answer: C
The radius ratio is 167/181=0.92, which lies in the cubic range 0.732-1.000. A cubic hole means each Cs+ is surrounded by 8 chloride ions, so the coordination number is 8 (6 would apply to NaCl).