JEE Main levelSingle correct optionDifficulty 2 of 3sb066
Take ionic radii BeX2+ = 31 pm and AlX3+ = 54 pm. The ratio (charge/radius of BeX2+) : (charge/radius of AlX3+) is closest to
A0.67
B1.74
C1.16
D0.86
Answer: C
Charge/radius for Be2+ is 2/31=0.0645 and for Al3+ is 3/54=0.0556pm−1. The ratio is 0.0645/0.0556=1.16. The two ions have similar polarising power, which underlies the diagonal relationship.