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JEE Main levelSingle correct optionDifficulty 2 of 3sb063

Assertion (A): Lithium carbonate decomposes on heating to give and , whereas sodium carbonate does not decompose at the same temperature. Reason (R): The small ion strongly polarises the carbonate ion and forms an oxide of high lattice enthalpy.

  1. ABoth A and R are true and R is the correct explanation of A
  2. BBoth A and R are true but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: A

Li+ has high polarising power, which weakens a C-O bond in , and the product has a large lattice enthalpy. Both facts favour , while the much larger Na+ polarises weakly. Both statements are true and R explains A.
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