JEE Main levelSingle correct optionDifficulty 2 of 3sb063
Assertion (A): Lithium carbonate decomposes on heating to give LiX2O and COX2, whereas sodium carbonate does not decompose at the same temperature.
Reason (R): The small LiX+ ion strongly polarises the carbonate ion and forms an oxide of high lattice enthalpy.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
Li+ has high polarising power, which weakens a C-O bond in COX3X2−, and the product LiX2O has a large lattice enthalpy. Both facts favour LiX2COX3LiX2O+COX2, while the much larger Na+ polarises weakly. Both statements are true and R explains A.