Answer: C
Hexane-3,4-diol gives propanal (Tollens positive, iodoform negative), hexane-2,3-diol gives two products (ethanal and butanal) and hexane-1,2-diol gives pentanal and methanal. Pinacol gives only propanone, which has a CH3CO group (iodoform positive) and does not reduce Tollens reagent.